一POE分子结构性能

Molecular structure properties of a POE

POE分子结构的特殊性使其综合性能相当优异

The specificity of POE molecular structure makes its comprehensive performance excellent.

作为增韧材料,POE具有添加量少、增韧效果明显、对基础树脂性能影响小等特点,这种新型高分子聚合物的出现引起了全球橡塑界的广泛关注,也为聚合物的改性和加工应用带来一个全新的理念；

As a toughening material, POE has the characteristics of little addition, obvious toughening effect and small influence on the properties of basic resin. The appearance of this new polymer has aroused wide attention in the global rubber and plastic circles, and it also brings a new idea for the modification and processing application of the polymer.

与其他传统弹性体相比POE具有以下主要特点：

Compared with other traditional elastomers, POE has the following main characteristics:

分子链结构中没有不饱和键,所含叔碳原子少,耐候性和热稳定性更优异；商品化POE呈颗粒状，可以直接加入到聚丙烯(PP)等粒状聚合物中,混合更均匀、更快速; 材料透明度高,未交联POE的密度比SBS和EVA低10%~20%；可用过氧化物、硅烷和辐射方法交联,交联POE的热老化及紫外光气候老化性能优于EPR和三元乙丙橡胶(EPDM)；较强的熔体强度、剪切敏感性和窄的相对分子质量分布,使材料边缘在加工中不易卷曲且弥补了挤出片材时材料易下垂和难以吹膜的缺陷; 力学性能平衡性与加工性优,一般弹性体门尼粘度低,加工性好，而力学性能差,常用弹性体门尼粘度在20~90之间，而POE的门尼粘度在5~35之间,但力学性能却能和高门尼粘度热塑性丁苯橡胶媲美。

There is no unsaturated bond in the molecular chain structure, which contains less tertiary carbon atoms and better weatherability and thermal stability; commercialized POE is granular and can be directly added to polypropylene (PP) and other granular polymers. The mixture is more uniform and faster; the transparency of the material is high, the density of unlinked POE is lower than SBS and EVA, and the peroxide and silane can be used. Cross linking with radiation methods, the thermal aging and ultraviolet light climate aging properties of cross linked POE are better than EPR and three proactive ethylene propylene rubber (EPDM). Strong melt strength, shear sensitivity and narrow relative molecular mass distribution make the edge of the material not easy to curl in processing and make up for the defects of the material easily drooping and difficult to blow film when extruding the sheet. The performance balance and processing property are excellent, the ordinary elastomer Mooney viscosity is low, the machinability is good, but the mechanical property is poor, the commonly used elastomer Mooney viscosity is between 20~90, and the Mooney viscosity of POE is between 5~35, but the mechanical properties can be compared to the high Mooney viscosity thermoplastic styrene butadiene rubber.

二

Two

POE再生颗粒产品性能描述

Performance description of POE regenerated particles

用于各种塑料的改性增韧注塑增韧，能有效改善各种塑料的韧性,耐寒性和抗冲击性，及撕裂强度，相容性好，可按任意比例添加，效果接近新料,应用：可同PP、PE. PA.共混（5%~8%)达到改性增韧的目的，聚烯烃POE作为一种添加剂，可用于掺入聚乙烯，聚丙烯和其它热塑性塑胶以改善产品的物理特性，也可以用作软质成型材料的树脂，POE一般用于对于一些杂色黑色破碎PP料的增韧。

The modified toughening and toughening of various plastics can effectively improve the toughness, cold resistance and impact resistance of all kinds of plastics, and the tearing strength and compatibility are good. It can be added at any proportion, and the effect is close to the new material. The application can be modified with PP and PE. PA. (5%~8%) for the purpose of modification and toughening. Polyolefin POE is used as an additive, It can be used in polyethylene, polypropylene and other thermoplastic plastics to improve the physical properties of the product, and can also be used as a resin for soft molding materials. POE is generally used for toughening of some colored black broken PP materials.